ESTERIFICATION OF OLEIC ACID AND ETHYL ALCOHOL FOR SYNTHESIS OF ETHYL OLEATE CATALYZED BY LIPASE IMMOBILIZED IN POLYURETHANE
The Candida antarctica lipase B immobilized on polyurethane catalysed esterification of oleic acid with ethyl alcohol in mechanical and ultrasonic agitation system in a system solvent-free organic, was studied. The maximum esterification of ethyl oleate was 1553.83 U/g with 19 cycles of reuse after 40 minutes of reaction time in mechanical system and 3087.60 U/g was observed and 14 cycles de reuse after 15 minutes of reaction time in ultrasound system. Thus, the process was considered efficient with significant reduction of the reaction time, low instrumental requirements and improve the bioprocess performance. Until now, there were no studies available in the open literature in relation to the ester synthesis catalyzed by immobilized lipase in polyurethane as support in the ultrasound system, especially in terms of esterification activity. In addition, considered an environmentally correct and economically viable technology, it can be used in cosmetics, pharmaceuticals, biodiesel and food industry.
ABOU-OKEIL, A. EL-SHAFIE, A. EL ZAWAHR, M.M. Ecofriendly laccase–hydrogen peroxide/ultrasound-assisted bleaching of linen fabrics and its influence on dyeing efficiency. Ultrason. Sonoch. v. 17, p. 383-390, 2010.
ADEWALE, P. DUMONT, M.J. NGADI, M. Enzyme-catalyzed synthesis and kinetics of ultrasonic assisted methanolysis of waste lard for biodiesel production. Chem. Eng. J. v. 284, p. 158164, 2016.
AZUDIN, N.Y., DON, M.M. SHUKOR, S.R.A. Production and Kinetics of Isoamyl Acetate from Acetic Anhydride using Candida antarctica Lipase B in a Solvent-Free System. J. Food Quality. v. 36, p. 441-445, 2013.
BANSODE, S.R. and RATHOD, V.K. Ultrasound assisted lipase catalyzed synthesis of isoamyl butyrate. Process Biochem. v. 49, p. 1297-1302, 2014.
BATISTELLA, L. LERIN, L. BRUGNEROTTO, A.J. DANIELLI, C.M. TRENTIN, A. POPIOLSKI, H. TREICHEL, H. OLIVEIRA, J.V. DE OLIVEIRA, D. Ultrasound-assisted lipase-catalyzed transesterification of soybean oil in organic solvent system. Ultras. Sonoch. v. 19, p. 452-460, 2012.
CARVALHO, A.K. FARIA, E.L. RIVALDI, J.D. ANDRADE, G.S. DE OLIVEIRA, P.C. DE CASTRO, H.F. Performance of whole-cells lipase derived from Mucor circinelloides as a catalyst in the ethanolysis of non-edible vegetable oils under batch and continuous run conditions. Ind. Crops Prod. v. 67, p. 287-293, 2015.
CHOUDHURY, H.A MALANI, R.S. MOHOLKAR, V.S. Acid catalyzed biodiesel synthesis from Jatropha oil: mechanistic aspects of ultrasonic intensification. Chem. Eng. J. v. 231, p. 262-270, 2013.
COLOMBO, T.S. MAZUTTI, M.A. DI LUCCIO, M. DE OLIVEIRA, D. OLIVERA, J.V. Enzymatic synthesis of soybean biodiesel using supercritical carbon dioxide as solvent in a continuous expanded-bed reactor. J. Superc. Fluids. v. 97, p. 16-22, 2015.
DESHMUKH, A.W. VARMA, M.N. YOO, C.K.E. WASEWAR, K.L. Effect of Ethyl Oleate Pretreatment on Drying of Ginger: Characteristics Mathematical Modelling. J. Chem. v. 1, p. 1-6, 2013.
DHAKE, K.P. THAKARE, D.D. BHANAGE, B.M. Lipase: A potential biocatalyst for the synthesis of valuable flavour and fragrance éster compounds. Flav. Fragr. J. v. 28, p. 71-80, 2013.
GARCIA‐GALAN, C. BERENGUER‐MURCIA, Á FERNANDEZ-LAFUENTE, R. RODRIGUES, R.C. Potential of different enzyme immobilization strategies to improve enzyme performance. Adv. Synth. Cat. v. 353, p. 2885-2890, 2011.
HIRATA, D.B. ALBUQUERQUE, T.L. RUEDA, N. VIRGEN-ORTÍZ, J.J. TACIAS-PASCACIO, V.G. FERNANDEZ-LAFUENTE, R. Evaluation of different immobilized lipases in transesterification reactions using tributyrin: Advantages of the heterofunctional octyl agarose beads. J. Mol. Catal. B: Enz. v. 133, p. 117-123, 2016.
ITSEKSON, A.M. SEIDMAN, D.S. ZOLTI, M. ALESKER. M.E. CARP, E.H.J. Steroid hormone hypersensitivity: clinical presentation and management. Fert. Steril. v. 8, p. 2571-2579, 2011.
KHAN, N.R. JADHAV, S.V. RATHOD, V.K. Lipase catalyzed synthesis of cetyl oleate using ultrasound: Optimization and kinetic studies. Ultras. Sonoch. v. 27, p. 522-528, 2015.
KHAN, N.R. and RATHOD, V.K. Enzyme catalyzed synthesis of cosmetic esters and its intensification: A review. Process Bioch. v. 50, p. 1793-1815, 2015.
KUMAR, P.P. KUMARAVEL, S. LALITHA, C. Screening of antioxidant activity, total phenolics and GC-MS study of Vitex negundo. African J. Biochem. Res. v. 4, p. 191-200, 2010.
KWIATKOWSKA, B. BENNETT, J. AKUNNA, J. WALKER, G.M. BREMNER, D.H. Stimulation of bioprocesses by ultrasound. Biotech. Adv. v. 29, p. 768-773, 2011.
LI L., JI F., WANG J., LI Y. BAO Y. Esterification degree of fructose laurate exerted by Candida antarctica lipase B in organic solvents. Enzym Microbial Technol. v. 69, p. 46-53, 2015.
LIU, Y. Q. JIN, L. SHAN, Y. LIU, W. SHEN, X. WANG, A. The effect of ultrasound on lipase-catalyzed hydrolysis of soy oil in solvent-free system. Ultrason. Sonoch. v. 15, p. 402-409, 2008.
MARTINS, A.B. FRIEDRICH, J.L. CAVALHEIRO, J.C. GARCIA-GALAN, C. BARBOSA, O. AYUB, M.A. FERNANDEZ-LAFUENTEC, R. Rodrigues, R. Improved production of butyl butyrate with lipase from Thermomyces lanuginosus immobilized on styrene–divinylbenzene beads. Bioresour. Techn. v. 134, p. 417-425, 2013.
MATTE, C.R. BORDINHÃO, C. POPPE, J.K. RODRIGUES, R.C. HERTZ, P.F. AYUB, M.A. Synthesis of butyl butyrate in batch and continuous enzymatic reactors using Thermomyces lanuginosus lipase immobilized in Immobead 150. J. Mol. Catal. B Enz. v. 127, p. 67-75, 2016.
MICHELIN, S. PENHA, F.M. SYCHOSKI, M.M. SCHERER, R.P. TREICHEL, H. VALÉRIO, A. OLIVEIRA, J.V. Kinetics of ultrasound-assisted enzymatic biodiesel production from Macauba coconut oil. Renew. Energ. v. 76, p. 388-394, 2015.
NYARI, N.L.D. FERNANDES, I.A. BUSTAMANTE-VARGA, C.E. STEFFENS, C.D. ZENI, J. DALLAGO, R.M. In situ immobilization of Candida antarctica B lipase in polyurethane foam support. J. Mol. Catal. B Enz. v. 124, p. 52-60, 2016.
ORELLANA-COCA, C.U. TÖRNVALL, D. ADLERCREUTZ, B. MATTIASSON, R. HATTI-KAUL, A. Chemo-enzymatic epoxidation of oleic acid and methyl oleate in solvent-free medium. Biocat. Biotransf. v. 23, p. 431-439, 2005.
POPPE, J. K., FERNANDEZ-LAFUENTE, R., RODRIGUES, R. C., AYUB, M. A. Z. Enzymatic reactors for biodiesel synthesis: present status and future prospects. Biotechnol Adv. v. 33, p. 511-525, 2015.
SANTIN, C.M., SCHERER, R.P., NYARI, N.L., DALLA ROSA, C., DALLAGO, R.M., DE OLIVEIRA, D., OLIVEIRA, J.V. Batch esterification of fatty acids charges under ultrasound irradiation using Candida antarctica B immobilized in polyurethane foam. Biocatalysis Agricultural Biotechnol. v. 3, p. 90-94, 2014,
TOMIN, A. HORNYÁNSZKY, G. KUPAI, K. DORKÓ, Z. ÜRGE, L. DARVAS, F. POPPE, L. Lipase-catalyzed kinetic resolution of 2-methylene-substituted cycloalkanols in batch and continuous-flow modes. Process Bioch. v. 45, p. 859-865, 2010.
WAGHMARE, G.V. VETAL, M.D. RATHOD, V.K. Ultrasound assisted enzyme catalyzed synthesis of glycerol carbonate from glycerol and dimethyl carbonate. Ultras. Sonoch. v. 22, p. 311-317, 2015.
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A Revista Inova Ciência & Tecnologia / Innovative Science & Technology Journal (RICT/ISTJ), publicada pela EDITORA IFTM, é bem avaliada pela Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES).
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